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Residual contamination of chlorinated solvents is commonly found in low-permeability formations. These contaminants serve as continuing sources to impact groundwater (i.e., back diffusion), significantly extending the remediation time frame. Hydraulic fracturing by high-pressure injection has been suggested as a useful alternative for permeability enhancement. The overarching objective of this project is to advance the fundamental understanding of particulate amendment (granular or powdered activated carbon) transport, compaction, and remedial efficacy in artificially-created hydraulic fractures in low-permeability clay formations contaminated by chlorinated volatile organic compounds (cVOC). The specific research aims are the followings:
Injection of GAC/Sand Particles Into a Fracture Model
Long-term Behaviors of Hydraulic Conductivity of a Fracture Created in Soil and Filled with GAC/Sand Particles
Previous studies have shown that the form of an artificially-created hydraulic fracture in a shallow low-permeability formation is generally predictable. However, there are still knowledge gaps between advanced understanding of fracture forms and effective delivery and placement of remediation amendments in hydraulic fractures. This project aims to address these fundamental questions using novel laboratory experiments and advanced modeling methods.
In Aim R1, a novel laboratory fracture slot system and a fluid/particle-coupled numerical transport model will be developed to investigate the transport and distribution of injected slurry particles in a model hydraulic fracture, where the fracture dip angle, injection flow rate, particle size, and GAC mixing ratio can be precisely controlled. In Aim R2, a custom-built laboratory fracture conductivity cell and a discrete element method/lattice Boltzmann-coupled model will be used to assess the compaction and embedment of a GAC/sand mixture in a hydraulic fracture created in low-permeability aquifer materials collected from a DoD site, as well as how particle amount, GAC mass mixing ratio, clay type, and water soaking time affect the change of fracture conductivity. In Aim R3, two representative flow cell experiments will be used to assess the release of cVOCs from a clay matrix, and from a heterogeneous low conductivity field. A reactive transport model will be modified and used to interpret the results and scale them to larger-scale systems.
New insights and empirical correlations from laboratory experiments and scalable numerical modeling tools will allow DoD site managers and remediation practitioners to predict how injection and subsurface lithology conditions affect the transport and distribution of amendments in hydraulic fractures in low-permeability formations, and the corresponding effectiveness in mitigating cVOC back diffusion. Specifically, the new insights and empirical correlations obtained from the laboratory experiments and numerical modeling studies will enable DoD site managers and other stakeholders to better predict GAC amendment transport and distribution in fractures across multiple spatial scales, which will be extremely valuable in optimized designs of field injection strategies for in situ environmental remediation at DoD sites. Possible product receivers include consulting companies who will use the tools developed from this project, the United States Environmental Protection Agency or other agencies that remediation practitioners interact with, and DoD site managers. (Anticipated Project Completion - 2025)