Reducing the potential magnitude of the impact of per- and polyfluoroalkyl substances (PFAS) at Department of Defense (DoD) installations will require a sustained effort to identify the best technologies to characterize, treat, and manage these sites. SERDP and ESTCP projects improve the current understanding of PFAS toxicity and behavior in the environment, as well as sampling and analysis of PFAS, to conduct efficient site investigations. We have funded hundreds of projects that have quickly and significantly advanced our understanding and management of PFAS in the environment by evaluating a range of potential treatment technologies, ecotoxicological effects, and improved site characterization. Our programs also fund the development and demonstration of PFAS-free firefighting formulations, which is covered under our Chemicals and Materials focus area. An overview of all PFAS investments is shown below.

Subtopics:
Occurrence, Fate, & Transport

Improved understanding in characterizing and modelling the nature of sources (and associated plumes) will lead to more targeted remediation strategies for sites posing the greatest risk. Several projects have been initiated to better understand the occurrence, fate and transport of PFAS in the environment.

Treatment of PFAS-Impacted Matrices

SERDP and ESTCP fund the development and demonstration of PFAS treatment technologies that include a wide variety of different processes and generally fall into the following categories: thermal treatment, treatment of investigation derived waste (IDW), biodegradation, in situ groundwater treatment, development of new sorbents, above-ground treatment, and the impact of co-occurring chemicals.

Sampling & Analysis

SERDP and ESTCP are focused on improving sampling and analysis for PFAS in environmental matrices. Significant efforts are underway to develop passive sampling methodologies, improve total organic fluorine (TOF), and develop a forensics approach to PFAS in the environment.

Ecotoxicity of PFAS

SERDP and ESTCP efforts to close knowledge gaps in ecotoxicity and ecological risk will aid in the development of appropriate site-specific risk assessments and help in decision-making related to mitigation of exposures and/or future environmental cleanup. Current projects are addressing impacts of PFAS to several species, including but not limited to avian, mammalian, and reptilian species.

2013
Workshop Report:
Long Term Mgmt of Contaminated Groundwater
2017
Workshop Report:
PFAS R&D Needs
    2022
Workshop Report:
PFAS R&D Needs
 2024
Ecotoxicity Workshop
 
   
        Coatings   
      Enhancements   
  Creation of Reference Material Ecotoxicity of PFAS-Free Formulations Mixture EcotoxicityAnalytical Methods PFAS-Free FormulationsConcentration Sequestration   
  Source Zones PFAS-Free Firefighting Formulations Marine EcotoxicityConcrete & AsphaltAnalytical & Sampling Methods   
  Investigation Derived Waste Biodegradation Avian Ecotoxicity & RiskStormwater ManagementDestructive Treatment Processes   
2011
In Situ Groundwater Remediation
 Groundwater RemediationMethod 1633 ValidationPassive Sampling  Impacted Material TreatmentTransformationFate & TransportTreatmentTransformation 
2014
In Situ Groundwater Remediation
Co-Occuring ChemicalsKnowledge GapsEcorisk CharacterizationLeaching & MobilityGroundwater Remediation AmendmentsEnhancementsPerformanceSelf-Assembly BehaviorPhysical-Chemical PropertiesEcotoxicity 
2016
Ecotoxicity
PFAS-Free Firefighting FormulationsPFAS-Free Firefighting FormulationsAnalytical & Sampling MethodsForensic Methods Thermal DestructionThermal Degradation in MunitionsTestingThermal DestructionImpacted MicroplasticsSensors 
2011 - 20162017201820192020202120222023202420252026 
2015
FAQs
Enhanced Persulfate OxidationIon Exchange & PlasmaPAC & FiltrationDestructionDestructionDestructionDestructionDestruction   
2016
Transport, Transformation & Retention
 Ex Situ TreatmentFoam FractionationConcentration SequestrationConcentration SequestrationConcentration SequestrationConcentration SequestrationConcentration Sequestration   
   Real-Time Analytical MethodsFirefighting Systems CleaningTreatment TrainPrototype TechnologiesExcavated Sediments TreatmentMonitoring Characterization   
   PFAS-Free Firefighting FormulationsMonitoring CharacterizationMonitoring CharacterizationMonitoring CharacterizationMonitoring CharacterizationManagement Tools   
  PFAS-Free Firefighting Formulations PFAS-Free Firefighting FormulationsTechnology TransitionAFFF Destruction   

 

 Treatment Ecotoxicity Fate, Transport and Characterization Analytical and Sampling Methods PFAS-Free AFFF Technology Transition