The U.S. Army has significantly invested in demilitarization technologies of conventional ammunition for the purpose of reducing the size of the demil stockpile. Conventional ammunition is defined in DoDD 5160.65 as an end item, complete round or materiel component charged with explosives, propellants, pyrotechnics, or initiating composition. It does not include chemical, biological, or nuclear munitions.
The demil stockpile contains approximately 400,000 tons of ammunition and about 27,000 tons of missiles. The focus of demil technology development has recently been on the top 400 items that combined, represent approximately 85% by weight of the total stockpile.
Demil technologies designed for single types of munitions present in large quantities are generally cost effective when evaluated on a cost per ton basis. This is not the case, however, for munitions present in small quantities. Unfortunately, most of the demil stockpile (by quantity) is represented by relatively small amounts of a wide variety of munitions. A single “omnivorous” system for a variety of whole munitions is needed to provide a cost effective, environmentally friendly alternative to OB and OD of these items. Whole item demilitarization traditionally includes unpacking the munitions (and disposal of dunnage), fuze removal (if present), disassembly to separate metal, explosives and propellant followed by disposal or recycling of components. Static detonation chambers and incinerators have been used for omnivorous disposal; however, throughput can be slow, resulting in high operating cost.
Future munitions containing insensitive high explosives (IHE), particularly those that are cast cured, is an emerging concern where an acceptable demil process does not currently exist. Current disposal methods for high explosives (HE) often rely on OD or recovery by melt-out and re-use as a donor charge material for OD. Historically, the U.S. military has preferred not to use recycled energetics in military weapons due to concerns over quality, stability of supply, and the cost and time to requalify the recovered energetic material. Insensitive high explosives, by design, are not good candidates for donor charges and reduced reliance on OB/OD projects a future capability gap for demilitarization. The explosive IMX 101, for example, is a qualified insensitive munition under NATO STANAG. The IMX formulation uses the melt cast ingredient 2,4-dinitroanisole (DNAN) together with nitroguanidine (NQ) and 3-nitro-1,2,4-triazol-5-one (NTO) as a substitute for TNT. Although studies have been conducted to evaluate physical, chemical and biological treatment of 3 soluble IMX constituents, innovative technologies for removal, collection and destruction of bulk quantities of IHE are needed for high throughput, cost effective destruction.
New explosive formulations that improve power and performance while maintaining insensitive characteristics are emerging for use in future weapons. These explosives may contain cast-cured polymers that can be extracted using high pressure washout techniques. However, these methods produce excessive amounts of wastewater and are not practical for small items. Novel approaches that predispose the weapon for explosive removal or whole system demilitarization, that utilize reversible cure chemistries to facilitate removal of explosives from small items and reduce waste water production, are needed to assure end-of-life technology options are available in the future.
Capability gaps exist for environmentally friendly, safe and cost effective demilitarization of pyrotechnics and illumination rounds, riot control agents, smoke producing munitions and munitions containing HC as bulk and primary fill. Omnivorous demilitarization in closed systems or platform technology that can be expanded or are designed to meet specific demil needs of each family of items do not currently exist. The family of riot control agents or munitions in the demil stockpile includes a variety of items that contain lacrimatory or irritating agents. Common fillers are tear gas, mace or pepper gas. Pyrotechnics, includes a variety of ammunition types used for illumination marking spotting, signaling, simulating or tracing. Typical items are ground, aircraft or marine illumination signal stars, photo flash cartridges, personnel distress kits, and air/ground burst simulators.